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            Sijuade, Ayomide Adeola; Eze, Vincent Obiozo; Arnett, Natalie Y; Okoli, Okenwa I (, Nanotechnology)Abstract Batteries and supercapacitors have emerged as promising candidates for next-generation energy storage technologies. The rapid development of new two-dimensional (2D) electrode materials indicates a new era in energy storage devices. MXenes are a new type of layered 2D transition metal carbides, nitrides, or carbonitrides that have drawn much attention because of their excellent electrical conductivity, electrochemical and hydrophilic properties, large surface area, and attractive topological structure. This review focuses on various synthesis methods to prepare vanadium carbide MXenes with and without etchants like hydrofluoric acid, lithium fluoride, and hydrochloric acid to remove the ‘A’ layers of the MAX phase. The goal is to demonstrate the utilization of a less toxic etching method to achieve MXenes of comparable properties to those prepared by traditional methods. The influence of intercalation on the effect of high interlayer spacing between the MXene layers and the performance of MXenes as supercapacitor and battery electrodes is also addressed in this review. Lastly, the gaps in the current knowledge for vanadium carbide MXenes in synthesis, scalability, and utilization in more energy storage devices were discussed.more » « less
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            Ekuase, Okunzuwa Austine; Anjum, Nafiza; Eze, Vincent Obiozo; Okoli, Okenwa I. (, Journal of Composites Science)Composite materials have gained increased usage due to their unique characteristic of a high-stiffness-to-weight ratio. High-performing composite materials are produced in the autoclave by applying elevated pressure and temperature. However, the process is characterized by numerous disadvantages, such as long cycle time, massive investment, costly tooling, and excessive energy consumption. As a result, composite manufacturers seek a cheap alternative to reduce cost and increase productivity. The out-of-autoclave (OoA) process manufactures composites by applying vacuum, pressure, and heat outside of the autoclave. This review discusses the common out-of-autoclave processes for various applications. The theoretical and practical merits and demerits are presented, and areas for future research are discussed.more » « less
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